Product ID:LESCO 4 BROAD SPECTRUM TURF FUNGICIDE
MSDS Date:11/08/1985
FSC:6840
NIIN:00N008928
MSDS Number: BCRJH

LESCO, INC.

20005 LAKE ROAD
ROCKY RIVER, OH 44116

Emergency Phone: 216-333-9250;CHEMTREC-800-424-9300

Info Phone: 216-333-9250

Cage: HO414

LESCO, INC.

ROCKY RIVER, OH 44116 US

Telephone: 216-333-9250

Cage: HO414

MANEB (SARA III)

CAS: 12427-38-2

RTECS: OP0700000

Fraction By Weight: <80%

ZINEB (SARA III)

CAS: 12122-67-7

RTECS: ZH3325000

Fraction By Weight: <80%

INERT INGREDIENTS

Fraction By Weight: 20%

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:LD50 RAT ORAL >8000 MG/KG (SEE SUP DATA)
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CHRONIC:SKIN IRRITATION,INFLAMMED
RETINA,APATHY,LOSS OF APPETITE,LOSS OF WEIGHT,WEAKNESS.
Explanation of Carcinogenicity:MANEB/ZINEB:CARCINOGENICITY IN HUMANS
NOT DETERMINED.INADEQUATE EVIDENCE FOR CARCINOGENICITY IN ANIMALS
(IARC 1976).
Effects of Overexposure:EYES:IRRITATION AND
INFLAMMATION.SKIN:IRRITATION AND INFLAMMATION.INGESTION:N/K
.INHALATION:IRRITATION AND INFLAMMATION OF NOSE AND THROAT.

First Aid:EYES:FLUSH WITH WATER FOR AT LEAST 15 MINUTES.SKIN:WASH WITH
SOAP & WATER.REMOVE CONTAMINATED CLOTHING.INGESTION:DILUTE BY
GIVING TWO GLASSES OF WATER.CALL PHYSICIAN OR POISON CONTROL
CENTER.NEVER GIV E ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON.INHALATION:REMOVE TO FRESH AIR.IF SYMPTOMS OCCUR,GET MEDICAL
ATTENTION.

Flash Point Method:TOC
Flash Point:295F,146C
Extinguishing Media:WATER SPRAY,DRY CHEMICAL,CARBON DIOXIDE.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROT
EQUIP .COOL FIRE-EXPOSED CNTNR W/ H*2O SPRAY.CONTAIN RUNOFF
H*2O.PVNT PRODUCT FROM ENTERING DRAINS,(SEE SUPP)
Unusual Fire/Explosion Hazard:TOXIC & FLAM GASES SUCH AS SULFUR &
NITROGEN OXIDES ARE EVOLVED ABOVE 176F,80C.EVACUATE PERSONNEL
DOWNWIND TO AVOID EXPOS TO SMOKE.DRIED PROD IS (SEE SUPP DATA)

Spill Release Procedures:SWEEP/SHOVEL INTO CONTAINERS FOR
REUSE/DISPOSAL.KEEP DUSTING TO A MINIMUM.FLUSH CONTAMINATED AREA
WITH WATER AND COLLECT.DO NOT ALLOW ENTRY INTO SEWERS,DRAINS,OR
BODIES OF WATER.REMOVE CONTAMINATED CL OTHING & WASH AFFECTED SKIN
WITH SOAP &WATER.
Neutralizing Agent:N/K

Handling and Storage Precautions:STORE IN A COOL,DRY PLACE.SEPARATE
FROM OTHER
PESTICIDES,FERTILIZERS,SEED,FEED,FOODSTUFFS,DRAINS,SEWERS & H*2O
SOURCES.KEEP CNTNR CLSD WHEN NOT IN USE
Other Precautions:PVNT FROM BECOMING WET/OVERHEATED.MATL IS COMBUST.DO
NOT IGNITE.STORE BAGGED MATL ON PALLETS NO MORE THAN 3 HIGH.DENSE
PACKING LEADS TO PRODUCT DECOMP POSING A FIRE HAZ & FOUL ODOR.STORE
ONLY IN MARKE T CNTNR.KEEP OUT OF REACH OF CHILDREN.

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR
CONCENTRATION BELOW TLV .
Protective Gloves:IMPERVIOUS MATERIAL.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:IMPERVIOUS BOOTS,CLEAN CLOTHING,EYEWASH
STATION & EMERGENCY SHOWER.
Work Hygienic Practices:N/K
Supplemental Safety and Health
SPECIAL FIRE FIGHTING PROC:DITCHES,SEWERS & OTHER BODIES OF
WATER.UNUSUAL FIRE & EXPLOS HAZ:COMBUSTIBLE.HAZ DECOMP PROD ARE
HYDROGEN SULFIDE AND CARBON DISULFIDE.LD50-LC50 MIXTURE:LD50 RABBIT
DERMAL > 5000 MG/KG.LC50 RAT INHALATION (4 HOUR)>1100 MG/CUM.BULK
DENSITY:0.35-0.50 G/CC.

Boiling Pt:B.P. Text:192C,378F
Melt/Freeze Pt:M.P/F.P Text:192-204C
Decomp Temp:Decomp Text:192-204C
Solubility in Water:DISPERSIBLE
Appearance and Odor:BLUE-GREEN POWDER,SLIGHT SULFUR ODOR.
Percent Volatiles by Volume:1-3

Stability Indicator/Materials to Avoid:YES
ACIDS,OXIDIZING MATERIALS.
Stability Condition to Avoid:MOISTURE,EXCESSIVE HEAT AND IGNITION
SOURCES.
Hazardous Decomposition Products:HYDROGEN SULFIDE,CARBON DISULFIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH
FEDERAL,STATE AND LOCAL REGULATIONS

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.